Sulpher dyes are complex heterocyclic molecules or
mixtures formed by melting or boiling organic compounds containing amino and
nitro group with Na polysulphide. Sulpher dyes are so called as they all
contain sulpher linkages within their molecules.
Dye - S - S – Dye + 2[H] = Dye
– SH + SH – Dye
[Water insoluble] [Water
soluble]
Dye – SH + SH – Dye + 2[o] = Dye - S - S
– Dye + H2O
[Water
soluble] [Water
insoluble]
Characteristics
of sulpher dye-
1.
Sulpher dyes have sulpher linkages within their
molecules.
2.
Sulpher dyes are highly colored water insoluble
dyes.
3.
They have no direct affinity towards cellulosic
fiber.
4.
Sulpher dyes have good light fastness with
rating about 4.
5.
These dyes have excellent wash fastness with
rating about 3-4.
6.
They are exclusively amorphous.
7.
Sulpher dyes are suitable for heavy and durable
shades.
8.
Sulpher dyes are cheap and easy to manufacture.
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